· jolie emphatically stated it was just brotherly love, stating to entertainment weekly: The siblings were visibly affectionate, holding hands and posing close. Angelina jolie arrived at the ceremony on the arm of her older brother , james haven. The infamous incident saw the movie star laying one on her brother , james haven, in 2000 at the oscars. · but perhaps few moments compare to when angelina jolie and her brother , james haven, made a bold declaration on the red carpet in 2000. My parents really loved that moment, and that’s what will always matter. In fact, this year marks 24 years since the. · it was the kiss. · with the oscars coming up, perhaps this is the best time to take a trip down memory lane and remember the infamous 2000 oscars ceremony when angelina jolie and her biological brother james went all jamie and cersei lannister on the red carpet. Of course, we’re talking about that kiss, when a relatively unknown angelina jolie locked inflatable lips with her brother and date james haven on the red carpet at the 2000 oscars.